SYNTHESIS AND STRUCTURAL FEATURES OF TETRANUCLEAR RHODIUM COMPLEXES OF AMIDOPHOSPHITO-AVITAND AND PHOSPHITOCAVITAND

Authors
NIFANTYEV EE MASLENNIKOVA VI GORYUKHINA SE VASYANINA LK LYSSENKO KA ANTIPIN MY
Citation
Ee. Nifantyev et al., SYNTHESIS AND STRUCTURAL FEATURES OF TETRANUCLEAR RHODIUM COMPLEXES OF AMIDOPHOSPHITO-AVITAND AND PHOSPHITOCAVITAND, Russian chemical bulletin, 47(9), 1998, pp. 1805-1811
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
47
Issue
9
Year of publication
1998
Pages
1805 - 1811
Database
ISI
SICI code
1066-5285(1998)47:9<1805:SASFOT>2.0.ZU;2-F
Abstract
Interactions of acetylacetonatodicarbonylrhodium(I) with amidophosphit o- and phosphitocavitands were studied. First representatives of tetra nuclear cavity complexes of rhodium(I) were obtained. It was establish ed by NMR spectroscopy and X-ray diffraction studies that the chemical ly identical phosphorhodium centers in these complexes differ in the s patial arrangement, and the system as a whole becomes unsymmetrical.