Ai. Vorobyova et al., SEM INVESTIGATION OF PILLARED MICROSTRUCTURES FORMED BY ELECTROCHEMICAL ANODIZATION, Applied physics A: Materials science & processing, 67(4), 1998, pp. 487-492
The results of SEM investigations of structured (pillared) layers form
ed by electrochemical processing of Al-Ta thin film sandwiches are pre
sented. The basic parameters of the internal microstructure and ''natu
ral'' morphology of Al anodic oxide films and pillared structured laye
rs formed on them are given. Two methods of multistep electrochemical
processing of aluminum films during porous anodic oxide films formatio
n were developed to improve the morphology of pillared microstructures
. Analysis of experimental data shows that the developed methods allow
us to obtain the ordered pillared microstructures with high aspect ra
tio (greater than or equal to 4), radius 15 to 35 nm, and pillar densi
ty (3.0 to 8.5) x 10(9) cm(-2). High reproducibility of physical and m
orphological parameters of the structured layers for large area sample
s is achieved. Such pillared matrices can be used for manufacturing of
the microelements based on the mesoscopic and quantum effects: solar
cells, controlled and uncontrolled emitter matrices for flat panel dis
plays and emission cathodes, cathode luminescent displays, functional
screens and polarizers for optoelectronics, etc.