PENTAAMMINENITROCOBALT(III) DICHLORIDE AT PRESSURES OF 0.24, 0.52, 1.25, 1.91 AND 3.38 GPA

Citation
Ev. Boldyreva et al., PENTAAMMINENITROCOBALT(III) DICHLORIDE AT PRESSURES OF 0.24, 0.52, 1.25, 1.91 AND 3.38 GPA, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1378-1383
Citations number
37
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
10
Pages
1378 - 1383
Database
ISI
SICI code
0108-2701(1998)54:<1378:PDAPO0>2.0.ZU;2-U
Abstract
The structure of [Co(NO2)(NH3)(5)]Cl-2 has been refined anisotropicall y from data collected at 0.24, 0.52, 1.25, 1.91 and 3.38 GPa in a diam ond anvil cell (DAC). For comparison, the structure of the same crysta l in the same DAC was also refined at ambient pressure. The structures at high pressures are anisotropically distorted compared with that at ambient pressure determined in this work and by Bortin [Acta Chem. Sc and. (1968), 22, 2890-2898],Kubota & Ohba [Acta Cryst. (1992), B48, 62 7-632] and Boldyreva et al. [Acta Cryst. (1997c), C53, 523-526], but t he space group and the general structural pattern remain the same.