1,4-DIMETHYLPYRIDINIUM ,5-DITHIOLATO)(ISOTHIOCYANATO)DIPHENYLSTANNATE(1-)

Authors
KHAN A LOW JN WARDELL JL FERGUSON G
Citation
A. Khan et al., 1,4-DIMETHYLPYRIDINIUM ,5-DITHIOLATO)(ISOTHIOCYANATO)DIPHENYLSTANNATE(1-), Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1399-1401
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
10
Pages
1399 - 1401
Database
ISI
SICI code
0108-2701(1998)54:<1399:1,>2.0.ZU;2-A
Abstract
in the title compound, 1,4-dimethylpyridinium (2-)-S-4,S-5](isothiocya nato)diphenylstannate(1-), (C7H10N)[Sn(NCS)(C6H5)(2)(C3S5)], the anion has distorted trigonal-bipyramidal coordination at the Sn atom, with the thiocyanato N and a thiolato S atom axial [Sn-N 2.262 (3), Sn-S 2. 5917(10) Angstrom and N-Sn-S 164.58(8)degrees]. The remaining thiolato S and two phenyl C atoms complete the equatorial coordination at Sn [ Sn-S 2.4399(10), and Sn-C 2.137 (4) and 2.139 (4) Angstrom].