TETRAETHYLAMMONIUM 3-DITHIOL-2-ONE-4,5-DITHIOLATO)DIETHYLSTANNATE(1-)

Citation
Zh. Chohan et al., TETRAETHYLAMMONIUM 3-DITHIOL-2-ONE-4,5-DITHIOLATO)DIETHYLSTANNATE(1-), Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1401-1403
Citations number
23
Categorie Soggetti
Crystallography
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
10
Pages
1401 - 1403
Database
ISI
SICI code
0108-2701(1998)54:<1401:T3>2.0.ZU;2-7
Abstract
In the title compound, tetraethylammonium 3-dithiol-2-onato(2-)-S-4,S- 5]diethylstannate(1-), [N(C2H5)(4)] [SnBr(C2H5)(2)(C3OS4)], the anion lies about a mirror plane and the Sn atom has distorted trigonal-bipyr amidal geometry, with axial distances Sn-Br 2.8776(16) and Sn-S 2.562( 2)Angstrom, and equatorial distances Sn-S 2.458(2) and Sn-C 2.111(7) A ngstrom. The [NEt4](+) cation is disordered about an inversion centre.