A CLOSO-12-VERTEX DINICKELABORANE - [(ETA(5)-C5H5)(2)NI2B10H10]

Authors
DOU JM HU CH GU JM NIE Y YAO HJ JIN RS ZHENG PJ
Citation
Jm. Dou et al., A CLOSO-12-VERTEX DINICKELABORANE - [(ETA(5)-C5H5)(2)NI2B10H10], Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1418-1419
Citations number
17
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
10
Pages
1418 - 1419
Database
ISI
SICI code
0108-2701(1998)54:<1418:ACD-[>2.0.ZU;2-V
Abstract
In the title compound, cyclopentadienyl-1,2-dinickela-closo-dodecabora ne, [Ni-2(B10H10)(C5H5)(2)], the cluster has a close-twelve-vertex ico sahedral {Ni2B10} framework. The Ni atoms occupy adjacent vertices of the polyhedron and each Ni atom is coordinated by a eta(5)-cyclopentad ienyl ring.