1,3-DIPHENYLGUANIDINIUM TRIFLUOROACETATE

Authors
PAIXAO JA SILVA PSP BEJA AM SILVA MR DAVEIGA LA
Citation
Ja. Paixao et al., 1,3-DIPHENYLGUANIDINIUM TRIFLUOROACETATE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1484-1486
Citations number
15
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
10
Pages
1484 - 1486
Database
ISI
SICI code
0108-2701(1998)54:<1484:1T>2.0.ZU;2-4
Abstract
The two phenyl rings of the title compound, C13H14N3+. CF3CO2-, assume a syn conformation with respect to the unsubstituted N atom of the ca tion. Bond lengths and angles within the guanidinium moiety are close to those expected for a central C-sp2 atom, accounting for some charge delocalization between the three C-N bonds. The structure is stabiliz ed by a two-dimensional network of intermolecular hydrogen bonds, wher e the carboxylate O atoms of the anions are accepters from the N-H gro ups of the diphenylguanidinium cations.