The structures of two substituted oxazolidinones, namely, 4-hydroxymet
hyl-4-methyloxazolidin-2-one [C5H9No3, (1)] and 4-ethyl-4-hydroxymethy
loxazolidin-2-one [C6H11NO3, (2)], are reported. Bond distances in the
two structures are almost identical. The oxazolidinone rings both ado
pt envelope conformations; the fold in (1) is significantly larger tha
n that in (2). There is no intramolecular hydrogen bonding in either s
tructure and the intermolecular hydrogen-bonding schemes are very simi
lar.