A SULTONE DERIVED FROM RACEMIC CAMPHENE

Authors
MUIR KW RODGER CS MORRIS DG RYDER KS
Citation
Kw. Muir et al., A SULTONE DERIVED FROM RACEMIC CAMPHENE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 1546-1548
Citations number
17
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
10
Pages
1546 - 1548
Database
ISI
SICI code
0108-2701(1998)54:<1546:ASDFRC>2.0.ZU;2-Y
Abstract
A controversy about the structures of five-membered ring sultones obta ined by treatment of camphenes with acetic and concentrated sulfuric a cids has been resolved by X-ray analysis of the sultone obtained from racemic camphene, namely, endo-3H-10, -dimethyl-4-oxa-5-thiatricyclo[5 .2.1.0(3,7)]decane S,S-dioxide, (also known as 10-bornanesulfonic acid 2-hydroxy-gamma-sultone), C10H16O3S Five-membered saturated sultone r ings are shown to be conformationally flexible.