Monolithic catalysts are becoming increasingly important in industrial
catalysis due to their low pressure drop at high gas hourly space vel
ocities. Compared to ceramic monoliths, metal monoliths are superior b
ecause of their ease of fabrication, higher mechanical strength, therm
al conductivity (hence uniform bed temperature), and thermal shock res
istance. This review describes briefly the potential applications of m
onolithic honeycomb catalysts in steam cracking to produce olefins and
aromatics, low-temperature and high-temperature catalytic combustion,
and of rotating monoliths as continuously regenerating reactors. Resu
lts are also presented on (a) controlled washcoating of alumina-whiske
r-covered metal monoliths, (b) the possibility to prepare monolith cat
alysts of variable activity, and (c) single-channel annular reactors (
SCAR) for monolith simulation and quick catalyst screening.