CATALYTIC AND STRUCTURAL-PROPERTIES OF THE ULTRADISPERSED SILVER POWDERS PREPARED BY ELECTROEXPLOSION TECHNIQUE - A COMPARISON WITH CONVENTIONAL SILVER CATALYSTS

Authors
BALZHINIMAEV BS ZAIKOVSKII VI PINAEVA LG ROMANENKO AV IVANOV GV
Citation
Bs. Balzhinimaev et al., CATALYTIC AND STRUCTURAL-PROPERTIES OF THE ULTRADISPERSED SILVER POWDERS PREPARED BY ELECTROEXPLOSION TECHNIQUE - A COMPARISON WITH CONVENTIONAL SILVER CATALYSTS, Kinetics and catalysis, 39(5), 1998, pp. 714-719
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
39
Issue
5
Year of publication
1998
Pages
714 - 719
Database
ISI
SICI code
0023-1584(1998)39:5<714:CASOTU>2.0.ZU;2-T
Abstract
The catalytic and structural properties of the ultradispersed powder ( UDP) of silver and a number of Ag-containing catalysts prepared by con ventional techniques were studied. The extremely high selectivity to e thylene oxide observed in the transformation of ethylene over the UDP of silver and Ag/C is probably related to the formation of specific ox ide-like structures that serve as a source of electrophilic oxygen nee ded for the reaction.