Ts. Zhuravleva et al., ULTRAFAST OPTICAL-RESPONSE OF IR-TREATED POLYACRYLONITRILE FILMS, Polymers for advanced technologies, 9(10-11), 1998, pp. 613-618
An ultrafast photoinduced optical response of infrared (heat) treated
polyacrylonitrile films (PAN-IR) was studied by a femtosecond pump-sup
ercontinuum probe technique in the energy region pf 1.6 - 3.2 eV. Two
types of films were used corresponding to 600 degrees C (Ist) and to 7
00 degrees C (2nd) heating. The samples were excited by optical pulses
with a duration of 50fsec and energy of (h) over bar w(pump) = 2.34eV
. The temporal evolution of the photoinduced response is characterized
by two relaxation times tau(1) and tau(2). For the 1st film type, the
spectral dependence of the ultrafast relaxation time shows nonmonoton
ous behavior, it decreases from tau(1) approximate to 170fsec to 70fse
c at 1.6 < (h) over bar w(probe) < 1.9eV and increases from tau(1) app
roximate to 80fsec to 140fsec at 1.9 < (h) over bar w(probe) < 3.2eV.
The spectral region 1.6-1.95eV corresponds to photoinduced darkening w
hile the region 1.95-3.2eV corresponds to photoinduced bleaching. For
the 2nd pm type, only photoinduced induced bleaching is observed, and
the ultrafast relaxation time decreases monotonously from tau(1) appro
ximate to 200fsec to tau(1) approximate to 70fsec. The second relaxati
on time tau(2) is Of similar to 1 psec for both types of films. (C) 19
98 John Wiley & Sons, Ltd.