A NOVEL CONVENIENT METHOD TO SYNTHESIZE UNSYMMETRICAL 1,1'-DISUBSTITUTED FERROCENES CONSISTING OF VARIOUS PHOSPHINO, THIOLATO AND PYRIDYL SUBSTITUENTS

Authors
DONG TY CHANG CK
Citation
Ty. Dong et Ck. Chang, A NOVEL CONVENIENT METHOD TO SYNTHESIZE UNSYMMETRICAL 1,1'-DISUBSTITUTED FERROCENES CONSISTING OF VARIOUS PHOSPHINO, THIOLATO AND PYRIDYL SUBSTITUENTS, Journal of the Chinese Chemical Society (Taipei), 45(5), 1998, pp. 577-579
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Journal of the Chinese Chemical Society (Taipei) → ACNP
ISSN journal
00094536
Volume
45
Issue
5
Year of publication
1998
Pages
577 - 579
Database
ISI
SICI code
0009-4536(1998)45:5<577:ANCMTS>2.0.ZU;2-R
Abstract
A novel convenient method for preparing unsymmetrical 1,1'-disubstitut ed ferrocenyl phosphine ligands by using the readily accessible 1,12'- diblomoferrocene as a precursor is described. The method is of interes t for modifying the chelating ferrocenyl phosphine ligands in view of the growing influence of homogeneous catalysis in organic synthesis, m anipulation of materials and production of high optical yield.