ALKOXIDE-ACCELERATED [1,3] SIGMATROPIC SHIFT OF BICYCLO[3.2.1]OCT-6-EN-2-OLS TO 8-ENDO-HYDROXYBICYCLO[3.3.0]OCT-2-EN-4-ONES

Authors
CHEN YL CHANG CK CHANG NC
Citation
Yl. Chen et al., ALKOXIDE-ACCELERATED [1,3] SIGMATROPIC SHIFT OF BICYCLO[3.2.1]OCT-6-EN-2-OLS TO 8-ENDO-HYDROXYBICYCLO[3.3.0]OCT-2-EN-4-ONES, Journal of the Chinese Chemical Society (Taipei), 45(5), 1998, pp. 649-653
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Journal of the Chinese Chemical Society (Taipei) → ACNP
ISSN journal
00094536
Volume
45
Issue
5
Year of publication
1998
Pages
649 - 653
Database
ISI
SICI code
0009-4536(1998)45:5<649:A[SSOB>2.0.ZU;2-D
Abstract
Bicyclo[3.2.1]oct-6-en-2-ols 6 are shown to undergo [1,3] sigmatropic shift to afford 8-endo-hydroxybicyclo[3.3.0]oct-2-en-4-ones 8 under th e influence of potassium hydride.