Da. Fiedler et al., CHARACTERIZATION OF STRONTIUM AND BARIUM MANGANATES BY ABRASIVE STRIPPING VOLTAMMETRY, Journal of solid state electrochemistry ( Journal of solid state electrochemistry (Print)), 2(6), 1998, pp. 413-419
Abrasive stripping voltammetry is applied in order to characterize bar
ium and strontium manganates-(V) and -(VI) in solid state phases. Volt
ammetric reduction peak potential values of KBaMnO4, Ba-3(MnO4)(2), Ba
-3(MnO4)(2-x)(BO3)(x) (x = 0.031(1)), Ba-5(MnO4)(3)OH, Ba-5(MnO4)(3)Cl
, Sr-5(MnO4)(3)OH and BaMnO4 are shown to be proportional to the corre
sponding average Mn-O distances, which were determined from X-ray powd
er diffractometric data through Rietveld refinement analyses.