Low-resolution long-slit spectra of reference stars, including MKK sta
ndard stars and well-known chemically peculiar stars, are used to deve
lop a spectroscopic method for the detection of the 5200 Angstrom flux
depression in CP stars. This new method is shown to be as sensitive a
detection tool as the photometrical techniques, and provides a higher
resolution view of the excess blocking. Application to stars in the f
ield of NGC 2244 allows us to estimate and eliminate reddening effects
. CP stars detected in this field include two members (#334 and #276)
of the very young stellar group NGC 2244 (age approximate to 3 x 10(6)
yr) and two or three foreground stars (#381, #625 and maybe #629). #3
34 and #625 are strongly peculiar.