HYDROLYSIS OF N-METHYL-N-NITROSO-P-TOLUENESULPHONAMIDE IN MICELLAR MEDIA

Authors
GARCIARIO L HERVES P LEIS JR MEJUTO JC PEREZJUSTE J
Citation
L. Garciario et al., HYDROLYSIS OF N-METHYL-N-NITROSO-P-TOLUENESULPHONAMIDE IN MICELLAR MEDIA, Journal of physical organic chemistry, 11(8-9), 1998, pp. 584-588
Citations number
23
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Journal of physical organic chemistry → ACNP
ISSN journal
08943230
Volume
11
Issue
8-9
Year of publication
1998
Pages
584 - 588
Database
ISI
SICI code
0894-3230(1998)11:8-9<584:HONIMM>2.0.ZU;2-4
Abstract
The acid and basic hydrolysis of N-methyl-N-nitroso-p-toluenesulphonam ide (MNTS) was studied in different micellar aggregates (CTACl, CTABr, TTABr, LTABr, and OTACl). The effect of mixed micelles (OTAX-LTAX) wa s also studied. The kinetic behaviour was explained on the basis of th e pseudophase model, from which the binding constants of MNTS to diffe rent micelles, the ion exchange constants and the reactivity constants in the micellar pseudophase were obtained. (C) 1998 John Wiley & Sons , Ltd.