SYNTHESIS OF THE PERHYDROINDOLE NUCLEUS BY A PUMMERER MANNICH INDUCEDCYCLIZATION CASCADE/

Citation
A. Padwa et Ag. Waterson, SYNTHESIS OF THE PERHYDROINDOLE NUCLEUS BY A PUMMERER MANNICH INDUCEDCYCLIZATION CASCADE/, Tetrahedron letters, 39(47), 1998, pp. 8585-8588
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
39
Issue
47
Year of publication
1998
Pages
8585 - 8588
Database
ISI
SICI code
0040-4039(1998)39:47<8585:SOTPNB>2.0.ZU;2-E
Abstract
The silicon-induced Pummerer reaction of several amido sulfoxides poss essing tethered pi-bonds proceeds by way of a thionium/N-acyliminium i on cascade to provide various azabicyclic ring systems. This cascade s equence was applied toward the synthesis of a member of the protoberbe rine alkaloid family. (C) 1998 Elsevier Science Ltd. All rights reserv ed.