A FACILE PREPARATION OF DIALKYL PHOSPHONATE COMPOUNDS FROM STERICALLYHINDERED P-NITROCUMYL HALIDES THROUGH THE S(RN)1 MECHANISM

Authors
RHEE JU RUSSELL GA BAIK W
Citation
Ju. Rhee et al., A FACILE PREPARATION OF DIALKYL PHOSPHONATE COMPOUNDS FROM STERICALLYHINDERED P-NITROCUMYL HALIDES THROUGH THE S(RN)1 MECHANISM, Tetrahedron letters, 39(47), 1998, pp. 8601-8604
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
47
Year of publication
1998
Pages
8601 - 8604
Database
ISI
SICI code
0040-4039(1998)39:47<8601:AFPODP>2.0.ZU;2-O
Abstract
p-Nitrobenzyl phosphonate anion with p-nitrocumyl halides gives a good yield of the coupling product dialkyl[(1,1-dimethyl-1,2-di-(p-nitrobe nzyl)ethyl] phosphonates through the S(RN)1 mechanism. The reaction wa s greatly accelerated by sunlamp irradiation but inhibited by the radi cal scavenger (t-Bu)(2)NO .. (C) 1998 Elsevier Science Ltd. All rights reserved.