SYNTHESIS OF O-ARYLENEDIZINE COMPOUNDS FROM 1-IODO-2-TRIFLUOROMETHYLSULFONYLOXYBENZENES AND ZINC POWDER AND THEIR SYNTHETIC APPLICATION

Authors
AMANO M SAIGA A IKEGAMI R OGATA T TAKAGI K
Citation
M. Amano et al., SYNTHESIS OF O-ARYLENEDIZINE COMPOUNDS FROM 1-IODO-2-TRIFLUOROMETHYLSULFONYLOXYBENZENES AND ZINC POWDER AND THEIR SYNTHETIC APPLICATION, Tetrahedron letters, 39(47), 1998, pp. 8667-8668
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
47
Year of publication
1998
Pages
8667 - 8668
Database
ISI
SICI code
0040-4039(1998)39:47<8667:SOOCF1>2.0.ZU;2-P
Abstract
1-Iodo-2-trifluoromethylsulfonyloxybenzenes readily reacted with Zn po wder to yield o-arylenedizine compounds, efficient synthetic equivalen ts of o-arylene dianions in Pd(0)-catalyzed cross-coupling reactions, wherein the novel insertion of Zn powder into the C-O bond of aryl tri flates took place. (C) 1998 Elsevier Science Ltd. All rights reserved.