HYDROGEN RETENTION PROPERTIES OF POLYCRYSTALLINE TUNGSTEN AND HELIUM IRRADIATED TUNGSTEN

The hydrogen retention properties of a polycrystalline tungsten and tu ngsten irradiated by helium ions with an energy of 5 keV were examined by using an ECR ion irradiation apparatus and a technique of thermal desorption spectroscopy, TDS. The polycrystalline tungsten was irradia ted at RT with energetic hydrogen ions, with a flux of 10(15) H cm(-2) s(-1) and an energy of 1.7 keV up to a fluence of 5 x 10(18) H cm(-2) . Subsequently, the amount of retained hydrogen was measured by TDS. T he heating temperature was increased from RT to 1000 degrees C, and th e heating rate was 50 degrees C min(-1). Below 1000 degrees C, two dis tinct hydrogen desorption peaks were observed at 200 degrees C and 400 degrees C. The retained amount of hydrogen was observed to be five ti mes smaller than that of graphite, but the concentration in the implan tation layer was comparable with that of graphite. Also, the polycryst alline tungsten was irradiated with 5 keV helium ions up to a fluence of 1.4 x 10(18) He cm(-2), and then re-irradiated with 1.7 keV hydroge n ions. The amount of retained hydrogen in this later experiment was c lose to the value in the case without prior helium ion irradiation. Ho wever, the amount of hydrogen which desorbed around the low temperatur e peak, 200 degrees C, was largely enhanced. The desorption amount at 200 degrees C saturated for the helium fluence of more than 5 x 10(17) He cm(-2). The present data shows that the trapping state of hydrogen is largely changed by the helium ion irradiation. Additionally, 5 keV helium ion irradiation was conducted on a sample pre-implanted with h ydrogen ions to simulate a helium ion impact desorption of hydrogen re tained in tungsten. The amount of the hydrogen was reduced as much as 50%. (C) 1998 Elsevier Science S.A. All rights reserved.