TETRAMETHYLAMMONIUM HYDROGENDIFLUORIDE - A CONVENIENT SOURCE OF NUCLEOPHILIC FLUORIDE

Authors
ADAMS DJ CLARK JH NIGHTINGALE DJ
Citation
Dj. Adams et al., TETRAMETHYLAMMONIUM HYDROGENDIFLUORIDE - A CONVENIENT SOURCE OF NUCLEOPHILIC FLUORIDE, Synthetic communications, 28(23), 1998, pp. 4295-4301
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
23
Year of publication
1998
Pages
4295 - 4301
Database
ISI
SICI code
0039-7911(1998)28:23<4295:TH-ACS>2.0.ZU;2-W
Abstract
Tetramethylammonium hydrogendifluoride (TMAHF(2)) acts as an effective fluoride source for the selective fluorination in high yields of vari ous chloro and nitroaromatics via halogen exchange (halex) and fluorod enitration.