STUDIES ON THE CIS DIHYDROXYLATION OF DRIMANEDIENE SKELETON

Authors
LECLAIRE M JEAN P RICARD L LALLEMAND JY
Citation
M. Leclaire et al., STUDIES ON THE CIS DIHYDROXYLATION OF DRIMANEDIENE SKELETON, Synthetic communications, 28(23), 1998, pp. 4371-4386
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
23
Year of publication
1998
Pages
4371 - 4386
Database
ISI
SICI code
0039-7911(1998)28:23<4371:SOTCDO>2.0.ZU;2-X
Abstract
The osmylation of dienic sulfone 4, a potential key intermediate in fo rskolin 1 and polyhydroxylated drimanes or labdanes derivatives, occur red exclusively on the Delta(6-7) double bound and preferentially from the alpha-face of the molecule (40-100% de). The influence of the sub stituent at C-l on the stereoselectivity of the reaction is studied.