A NEW, MODULATED, OXIDATIVE RING-CLEAVAGE OF ALPHA-NITROCYCLOALKANONES BY OXONE(R) - SYNTHESIS OF ALPHA,OMEGA-DICARBOXYLIC ACIDS AND ALPHA,OMEGA-DICARBOXYIIC ACID MONOMETHYL ESTERS

Authors
BALLINI R CURINI M EPIFANO F MARCOTULLIO MC ROSATI O
Citation
R. Ballini et al., A NEW, MODULATED, OXIDATIVE RING-CLEAVAGE OF ALPHA-NITROCYCLOALKANONES BY OXONE(R) - SYNTHESIS OF ALPHA,OMEGA-DICARBOXYLIC ACIDS AND ALPHA,OMEGA-DICARBOXYIIC ACID MONOMETHYL ESTERS, Synlett, (10), 1998, pp. 1049
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
10
Year of publication
1998
Database
ISI
SICI code
0936-5214(1998):10<1049:ANMORO>2.0.ZU;2-3
Abstract
By the appropriate choice of the reaction conditions Oxone(R) produces the ring cleavage of alpha-nitrocycloalkanones affording good yields of alpha,omega-dicarboxylic acids and alpha,omega-dicarboxylic acid mo nomethyl esters, respectively, regardless the ring size and/or the pre sence of an alkyl group as substituent.