STEREOSELECTIVE SYNTHESIS OF 2,3,5-SUBSTITUTED TETRAHYDROFURANS BY SILICON-DIRECTED CYCLIZATION OF ALLYLSILANES BEARING A HYDROXY MOIETY

Authors
AKIYAMA T ISHIDA Y
Citation
T. Akiyama et Y. Ishida, STEREOSELECTIVE SYNTHESIS OF 2,3,5-SUBSTITUTED TETRAHYDROFURANS BY SILICON-DIRECTED CYCLIZATION OF ALLYLSILANES BEARING A HYDROXY MOIETY, Synlett, (10), 1998, pp. 1150
Citations number
49
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
10
Year of publication
1998
Database
ISI
SICI code
0936-5214(1998):10<1150:SSO2TB>2.0.ZU;2-2
Abstract
Acid promoted cyclization of bishomoallylic alcohols bearing allylsila nes proceeded smoothly by way of beta-silyl carbocation intermediate t o furnish tetrahydrofurans highly stereoselectively.