An analytical expression for the maximal Lyapunov exponent lambda(1) i
n generalized Fermi-Pasta-Ulam oscillator chains is obtained. The deri
vation is based on the calculation of modulational instability growth
rates for some unstable periodic orbits. The result is compared with n
umerical simulations and the agreement is good over a wide range of en
ergy densities epsilon. At very high energy density the power law scal
ing of lambda(1) with epsilon can be also obtained by simple dimension
al arguments, assuming that the system is ruled by a single time scale
. Finally, we argue that for repulsive and hard fore potentials in one
dimension lambda(1) similar to root epsilon at large epsilon.