ABOUT FORMATION OF LOW-REACTIVE IN RESPECT TO INTERACTION WITH EACH OTHER AND WITH OXYGEN ALKYL RADICALS IN REACTION OF LOW-TEMPERATURE LIQUID-PHASE OXIDATION OF HEXAFLUOROPROPYLENE BY MOLECULAR-OXYGEN

Authors
SHAPOVALOV VV
Citation
Vv. Shapovalov, ABOUT FORMATION OF LOW-REACTIVE IN RESPECT TO INTERACTION WITH EACH OTHER AND WITH OXYGEN ALKYL RADICALS IN REACTION OF LOW-TEMPERATURE LIQUID-PHASE OXIDATION OF HEXAFLUOROPROPYLENE BY MOLECULAR-OXYGEN, Teoreticeskaa i eksperimentalnaa himia, 34(4), 1998, pp. 247-249
Citations number
9
Categorie Soggetti
Chemistry Physical
Journal title
Teoreticeskaa i eksperimentalnaa himia → ACNP
ISSN journal
04972627
Volume
34
Issue
4
Year of publication
1998
Pages
247 - 249
Database
ISI
SICI code
0497-2627(1998)34:4<247:AFOLIR>2.0.ZU;2-S
Abstract
It has been shown that there are kinetic proofs of participation of st able alkyl radicals in reaction of low-temperature liquid-phase oxidat ion of hexafluoropropylene by molecular oxygen. The proofs are non-par ticipation of alkyl radicals in the chain termination as well as forma tion of epoxide with considerable rates under high pressures of oxygen .