Ap. Filippov et al., FORMATION OF NANOPERIODIC STRUCTURES BASED ON KEGGIN AND LACUNARY ANIONS OF PHOSPHOTUNGSTIC ACID AND CATIONIC SURFACTANTS, Teoreticeskaa i eksperimentalnaa himia, 34(4), 1998, pp. 250-256
Surfactant cations (A(+)) in aqueous medium with pH 1.0 and in excess
of phosphotungstic acid form compounds of A(3)[PW12O40] composition, w
hile in the medium with pH 4.5 - A(n)H(7-n)[PW11O39]. xH(2)O acid salt
s, all of them having nanoperiodic structures. The parameters of the s
tructures are essentially dependent on the surfactant nature as well a
s on the type of heteropoly ion.