SYNTHESIS OF DIMETHYL 4-THIAZOLIDINYLPHOSPHINE OXIDES VIA ADDITION OFDIMETHYLPHOSPHINE OXIDE TO 3-THIAZOLINES

Authors
GROGER H TEHRANFAR D MARTENS J GOERLICH JR THONNESSEN H JONES PG SCHMUTZLER R
Citation
H. Groger et al., SYNTHESIS OF DIMETHYL 4-THIAZOLIDINYLPHOSPHINE OXIDES VIA ADDITION OFDIMETHYLPHOSPHINE OXIDE TO 3-THIAZOLINES, Heteroatom chemistry, 8(3), 1997, pp. 207-215
Citations number
38
Categorie Soggetti
Chemistry
Journal title
Heteroatom chemistry → ACNP
ISSN journal
10427163
Volume
8
Issue
3
Year of publication
1997
Pages
207 - 215
Database
ISI
SICI code
1042-7163(1997)8:3<207:SOD4OV>2.0.ZU;2-D
Abstract
The addition of dimethylphosphine oxide and its trimethylsiloxyphospho rus(III) derivative, generated in situ, to 3-thiazolines was found to yield dimethyl 4-thiazolidinylphosphine oxides via three different syn thetic routes. The structures of two products were confirmed by X-ray analysis; common features include approximate envelope conformations o f the five-membered rings and hydrogen bonding of the form N-H...O = P . (C) 1997 John Wiley & Sorts, Inc.