INCLUSION AND SEPARATION OF LUTIDINE ISOMERS BY A DIOL HOST COMPOUND

Citation
Mr. Caira et al., INCLUSION AND SEPARATION OF LUTIDINE ISOMERS BY A DIOL HOST COMPOUND, Supramolecular chemistry (Print), 9(3), 1998, pp. 231-237
Citations number
16
Categorie Soggetti
Chemistry
ISSN journal
10610278
Volume
9
Issue
3
Year of publication
1998
Pages
231 - 237
Database
ISI
SICI code
1061-0278(1998)9:3<231:IASOLI>2.0.ZU;2-A
Abstract
Structures of the inclusion compounds formed between the host compound 1,1-bis(4-hydroxyphenyl)cyclohexane and selected lutidine isomers hav e been elucidated. The activation energies and kinetics of desolvation for the complexes were determined. Competition experiments were perfo rmed to investigate preferential enclathration. Lattice energy calcula tions explain the results of the competition experiments.