THE FORMATION OF 3-CHLORO-1,2,5-THIADIAZOLES FROM ALPHA-OXIMIDONITRILES - OPTIMIZATION AND MECHANISTIC INSIGHTS

Authors
MCGILL JM MILLER MS
Citation
Jm. Mcgill et Ms. Miller, THE FORMATION OF 3-CHLORO-1,2,5-THIADIAZOLES FROM ALPHA-OXIMIDONITRILES - OPTIMIZATION AND MECHANISTIC INSIGHTS, Heterocycles, 48(10), 1998, pp. 2111-2123
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
48
Issue
10
Year of publication
1998
Pages
2111 - 2123
Database
ISI
SICI code
0385-5414(1998)48:10<2111:TFO3FA>2.0.ZU;2-J
Abstract
The optimized formation of substituted 3-chloro-1,2,5-thiadiazoles (2) and (3) from the alpha-oximidonitrile (4) is described. New mechanist ic insight into the formation of 3-chloro-1,2,5-thiadiazoles comes fro m the identification of a reaction intermediate in the thiadiazole rin g-forming reaction.