TRANSITION-METAL SUBSTITUTED PHOSPHANES, ARSANES AND STIBANES, LIX - AN ADDUCT OF THE ME3P-SUBSTITUTED FERRIO-DIPHENYLPHOSPHANE CP(OC)(ME3P)FE-PPH2 AND METHYLISOTHIOCYANATE - SYNTHESIS, PROTONATION, AND METHYLATION

Authors
MALISCH W SPORL A THIRASE K FEY O
Citation
W. Malisch et al., TRANSITION-METAL SUBSTITUTED PHOSPHANES, ARSANES AND STIBANES, LIX - AN ADDUCT OF THE ME3P-SUBSTITUTED FERRIO-DIPHENYLPHOSPHANE CP(OC)(ME3P)FE-PPH2 AND METHYLISOTHIOCYANATE - SYNTHESIS, PROTONATION, AND METHYLATION, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 53(10), 1998, pp. 1077-1083
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
53
Issue
10
Year of publication
1998
Pages
1077 - 1083
Database
ISI
SICI code
0932-0776(1998)53:10<1077:TSPAAS>2.0.ZU;2-R
Abstract
Treatment of the ferrio-phosphane Cp(OC)(2)Fe-PPh2 (1) with Me3P (2) y ields Cp(OC)(Me3P)Fe-PPh2 (3) via GO-substitution. Reaction of 3 with methylisothiocyanate (4) leads to the formation of the adduct Cp(OC)(M e3P)Fe-PPh2-C(S)NMe (5), which is regioselectively methylated at the s ulfur atom with MeI (6a) or MeSO3CF3 (6b), respectively, to give the c ationic complexes [Cp(OC)(Me3P)Fe-PPh2-C(SMe)=NMe]I/CF3SO3 (7a,b). In contrast, protonation with CF3SO3H (8) occurs at the nitrogen atom, yi elding [Cp(OC)(Me3P)Fe-PPh2-C(S)-N(H)Me] CF3SO3 (9). The structures of 7b and 9 have been determined by X-ray diffraction analysis.