PHOTOCHEMICAL REDUCTIVE ELIMINATION OF NITROGEN FROM TRIAZIDOGALLIUM(III) - GENERATION OF LUMINESCENT GALLIUM(I)

Authors
KUNKELY H VOGLER A
Citation
H. Kunkely et A. Vogler, PHOTOCHEMICAL REDUCTIVE ELIMINATION OF NITROGEN FROM TRIAZIDOGALLIUM(III) - GENERATION OF LUMINESCENT GALLIUM(I), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 53(10), 1998, pp. 1180-1182
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
53
Issue
10
Year of publication
1998
Pages
1180 - 1182
Database
ISI
SICI code
0932-0776(1998)53:10<1180:PREONF>2.0.ZU;2-W
Abstract
The irradiation of Ga(N-3)(3) in CH3CN leads to a reductive eliminatio n of nitrogen according to the equation Ga-III(N-3)(3) --> (GaN3)-N-I + 3N(2) (phi = 0.002 at lambda(irr) = 254 nm). Ga+ in CH3CN is charact erized by its absorption (lambda(max) = 298 nm) and emission (lambda(m ax) = 475 nm) spectrum.