[MOBR(CO)(2)(KAPPA(2)(P,P)-DPPM)(2)][PF6] (DPPM = PH2PCH2PPH2) - A 7-COORDINATE MOLYBDENUM(II)-DICARBONYL COMPLEX SHOWING A CAPPED OCTAHEDRON GEOMETRY

Authors
ZHANG L GAMASA MP GIMENO J GARCIAGRANDA S BORGE J
Citation
L. Zhang et al., [MOBR(CO)(2)(KAPPA(2)(P,P)-DPPM)(2)][PF6] (DPPM = PH2PCH2PPH2) - A 7-COORDINATE MOLYBDENUM(II)-DICARBONYL COMPLEX SHOWING A CAPPED OCTAHEDRON GEOMETRY, Anales de quimica, 94(2), 1998, pp. 84-87
Citations number
26
Categorie Soggetti
Chemistry
Journal title
Anales de quimica → ACNP
ISSN journal
11302283
Volume
94
Issue
2
Year of publication
1998
Pages
84 - 87
Database
ISI
SICI code
1130-2283(1998)94:2<84:[(=P-A>2.0.ZU;2-7
Abstract
The synthesis of bromodicalbonylbis[bis(diphenylphosphino) methane -ka ppa(2)P] molybdenum (II) hexafluorophosphate complex (C52N44 BrF6MoO2P 5. 2CH(2)Cl(2)) is described. The complex has been characterized by IR and P-31{H-1}-NMR spectroscopy. The structure has been determined by X-ray diffraction methods. It crystallizes in the monoclinic space gro up C2/c, Z = 8, a = 42.71(1) Angstrom, b = 11.47(1) Angstrom, c = 26.7 2(1) Angstrom, and beta = 118.58(1)degrees 9. The structure determinat ion shows a capped octahedron geometry around the molybdenum atom.