A MU-OXO DIIRON COMPLEX OF A NEW BINUCLEATING TETRAPYRIDYL LIGAND

Authors
BERCHET L COLLOMBDUNANDSAUTHIER MN DUBOURDEAUX P MONETA W DERONZIER A LATOUR JM
Citation
L. Berchet et al., A MU-OXO DIIRON COMPLEX OF A NEW BINUCLEATING TETRAPYRIDYL LIGAND, Inorganica Chimica Acta, 282(2), 1998, pp. 243-246
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
282
Issue
2
Year of publication
1998
Pages
243 - 246
Database
ISI
SICI code
0020-1693(1998)282:2<243:AMDCOA>2.0.ZU;2-A
Abstract
The new hexadentate ligand 2,11-bis-(N,N-[bis-(2-methylpyridyl)amino] methyl)benzo[c]phenanthrene has been designed to hold and stabilize a (mu-oxo)diiron(III) unit. Its synthesis and that of a (CL-oxo) (bis-mu -carboxylato)diiron(III) complex are described. The iron compound is c haracterized by several physicochemical techniques: UV-Vis spectroscop y, magnetism, electrochemistry and mass spectrometry. The latter techn ique shows the binuclear (as opposed to tetranuclear) nature of the co mpound. (C) 1998 Elsevier Science S.A. All rights reserved.