CONCERNING THE RESISTIVITY ANOMALY IN THE LAYERED PNICTIDE OXIDE NA2TI2SB2O

Citation
Ff. Debiani et al., CONCERNING THE RESISTIVITY ANOMALY IN THE LAYERED PNICTIDE OXIDE NA2TI2SB2O, Inorganic chemistry, 37(22), 1998, pp. 5807-5810
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00201669
Volume
37
Issue
22
Year of publication
1998
Pages
5807 - 5810
Database
ISI
SICI code
0020-1669(1998)37:22<5807:CTRAIT>2.0.ZU;2-J
Abstract
The origin of the resistivity anomaly at 120 K in the layered pnictide oxide Na2Ti2Sb2O is discussed on the basis of tight-binding band stru cture calculations. The Fermi surface of this material is shown to res ult from the superposition of a two-dimensional and four pseudo-one-di mensional components. It is proposed that the resistivity anomaly is a ssociated with a Fermi surface instability of these pseudo-one-dimensi onal portions leading to a periodic lattice distortion.