Authors
Citation
Mh. Schmidt et al., KINETICS OF 2-HALOPYRIDINE SUBSTITUTION AT PENTAAMMINEAQUARUTHENIUM(II), Inorganic chemistry, 37(22), 1998, pp. 5948
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00201669
Volume
37
Issue
22
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:22<5948:KO2SAP>2.0.ZU;2-3
Abstract
In this work, 2-halopyridines were found to have substitution rate con
stants greater than those for other substituted pyridines previously s
tudied, suggesting an effect of ligand polarity on substitution rates.
It was also found that nucleophilic attack on the 2-chloropyridine wa
s catalyzed by binding to the ruthenium complex.