Mg. Sedigh et al., EXPERIMENTS AND SIMULATION OF TRANSPORT AND SEPARATION OF GAS-MIXTURES IN CARBON MOLECULAR-SIEVE MEMBRANES, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 102(44), 1998, pp. 8580-8589
We report here the results of our recent studies describing the prepar
ation of carbon molecular sieve membranes, their separation and transp
ort characteristics with gas mixtures, and their molecular simulation.
Poly(furfuryl alcohol) (PFFA) was used as the polymeric precursor for
the preparation of the carbon films. The membranes were tested using
single gases H-2, CO2 CO,CH4, and Ar, as well as binary mixtures of CO
2/CH4 and a four-gas mixture consisting of CO2/CO/H-2/CH4. Separation
factors for CO2/CH4 in the range of 34-37 were obtained for the binary
and, the;four-gas mixtures. The membrane permeance decreased slowly d
uring continuous testing with the four-gas mixture. This decline in pe
rformance was found, however, to be reversible. The initial membrane p
ermeance was recovered by heating the membrane in an inert atmosphere
of Ar. Modeling of the membrane's transport characteristics was carrie
d out using a nonequilibrium molecular dynamics simulation. The modeli
ng results agree qualitatively with the experimental data.