HYDROLYSIS OF SPIROPHOSPHORANES WITH A SATURATED 1,3,2-DIOXAPHOSPHORINANE RING - X-RAY STRUCTURE OF THE INTERMOLECULARLY H-BONDED PHOSPHATEESTER (OCH2CME2CH2O)P(O)(2,2'-O-C6H4-C6H4OH)

Authors
SWAMY KCK SAID MA KUMARASWAMY S HERBSTIRMER R PULM M
Citation
Kck. Swamy et al., HYDROLYSIS OF SPIROPHOSPHORANES WITH A SATURATED 1,3,2-DIOXAPHOSPHORINANE RING - X-RAY STRUCTURE OF THE INTERMOLECULARLY H-BONDED PHOSPHATEESTER (OCH2CME2CH2O)P(O)(2,2'-O-C6H4-C6H4OH), Polyhedron, 17(20), 1998, pp. 3643-3648
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
17
Issue
20
Year of publication
1998
Pages
3643 - 3648
Database
ISI
SICI code
0277-5387(1998)17:20<3643:HOSWAS>2.0.ZU;2-E
Abstract
Hydrolysis of (6,5), (6,7) and (6,8)-spirophosphoranes containing the six-membered ring P(OCH2CMe2CH2O) has been studied; in all the cases t he six-membered phosphorinane ring is retained during the first stage of hydrolysis. The X-ray structure of one such product, (OCH2CMe2CH2O) P(O)(2,2'-O-C6H4-C6H4OH) which exhibits intermolecular H-bonding, has been determined. O 1998 Elsevier Science Ltd. All rights reserved. (C ) 1998 Elsevier Science Ltd. All rights reserved.