A LONG-LIVED E-2 STATE FOR A CR(III)N-6 AMINE CHROMOPHORE AT 298 K - [CR(FAC-ME-5-D(3H)TRICOSANEN(6))]CL-3

Authors
BROWN KN GEUE RJ MORAN G RALPH SF RIESEN H SARGESON AM
Citation
Kn. Brown et al., A LONG-LIVED E-2 STATE FOR A CR(III)N-6 AMINE CHROMOPHORE AT 298 K - [CR(FAC-ME-5-D(3H)TRICOSANEN(6))]CL-3, Chemical communications, (21), 1998, pp. 2291-2292
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
21
Year of publication
1998
Pages
2291 - 2292
Database
ISI
SICI code
1359-7345(1998):21<2291:ALESFA>2.0.ZU;2-W
Abstract
The E-2 state lifetime of the C-3 ion [Cr(fac-Me-5-D(3h)tricosaneN(6)) ](3+) is 235 mu s in H2O and 1.5 ms in D2O at 298 K, the longest lifet imes yet reported for a saturated Cr(III)N-6 chromophore at room tempe rature.