A. Dolbecq et al., [MO9S8O12(OH)(8)(H2O)(2)](2-) - A NOVEL POLYOXOTHIOMOLYBDATE WITH A MO-VI OCTAHEDRON ENCAPSULATED IN A REDUCED MO-V CYCLIC OCTANUCLEAR CORE, Chemical communications, (21), 1998, pp. 2293-2294
The novel polyoxothioanion [Mo9S8O12(OH)(8)(H2O)(2)](2-) was prepared
from the acido-basic condensation of four {(Mo2S2O2)-S-v} building uni
ts around a central {(MoO6)-O-VI} octahedron, the anion was characteri
zed by X-ray diffraction as a tetramethylammonium salt.