SOLID-STATE PHOTOCHEMICAL-REACTION OF ACHIRAL N-(BETA,GAMMA-UNSATURATED CARBONYL)THIOCARBAMATE TO OPTICALLY-ACTIVE THIOLACTONE IN THE CHIRAL CRYSTALLINE ENVIRONMENT

Authors
SAKAMOTO M TAKAHASHI M ARAI T SHIMIZU M YAMAGUCHI K MINO T WATANABE S FUJITA T
Citation
M. Sakamoto et al., SOLID-STATE PHOTOCHEMICAL-REACTION OF ACHIRAL N-(BETA,GAMMA-UNSATURATED CARBONYL)THIOCARBAMATE TO OPTICALLY-ACTIVE THIOLACTONE IN THE CHIRAL CRYSTALLINE ENVIRONMENT, Chemical communications, (21), 1998, pp. 2315-2316
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
21
Year of publication
1998
Pages
2315 - 2316
Database
ISI
SICI code
1359-7345(1998):21<2315:SPOAN>2.0.ZU;2-R
Abstract
O-Methyl N-(2,2-dimethylbut-3-enoyl)-N-phenylthiocarbamate crystallize d in the chiral space group P2(1), and the solid state photoreaction i nitiated intramolecular [2+2] thietane formation followed by rearrange ment, leading to optically active gamma-thiolactone.