FACILE OXIDATION OF A CARBAPORPHYRIN AT THE INTERNAL CARBON-ATOM - SYNTHESIS OF NOVEL BENZO[18]ANNULENE KETALS

Authors
HAYES MJ SPENCE JD LASH TD
Citation
Mj. Hayes et al., FACILE OXIDATION OF A CARBAPORPHYRIN AT THE INTERNAL CARBON-ATOM - SYNTHESIS OF NOVEL BENZO[18]ANNULENE KETALS, Chemical communications, (21), 1998, pp. 2409-2410
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
21
Year of publication
1998
Pages
2409 - 2410
Database
ISI
SICI code
1359-7345(1998):21<2409:FOOACA>2.0.ZU;2-8
Abstract
Treatment of benzocarbaporphyrin 2 with refluxing FeCl3 in CHCl3-alcoh ol mixtures leads to a remarkably selective oxidation at the interior carbon atom to produce dialkoxy products 5; these species show potenti ally valuable long wavelength absorptions in their UV-VIS spectra.