Ca. King et al., LATERAL ETCHING AND FILLING OF HIGH-ASPECT-RATIO NANOMETER-SIZE CAVITIES FOR SILICON DEVICE STRUCTURES, Applied physics letters, 73(20), 1998, pp. 2947-2949
e study a process technique involving SiO2 lateral etching coupled wit
h amorphous Si (alpha-Si) are filling as a possible alternative to imp
rove performance and lower costs for bipolar complementary metal-oxide
semiconductor technologies. We investigated the lateral etching of ox
ide layers with thicknesses between 50 and 2.5 nm confined between a S
i substrate and a multilayer stack composed of polycrystalline Si, WSi
x, and Si3N4. We found that the lateral etching of SiO2 proceeds even
with the smallest thickness (2.5 nm) to create extremely small cavitie
s. The etch extent (fixed time) dependence with SiO2 thickness suggest
s that capillary action may be an important mechanism. Using standard
amorphous Si deposition techniques, we refilled all the small cavities
without void formation as witnessed from transmission electron microg
raphs. [S0003-6951(98)01346-1].