V. Torra et H. Tachoire, CONDUCTION CALORIMETERS - HEAT TRANSMISSION-SYSTEMS WITH UNCERTAINTIES, JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 52(3), 1998, pp. 663-681
A critical reading of early papers on heat flux or conduction calorime
try (1920-1965) reveals the original kinetic aims of the developed ins
trumentation and the progressive appearance of the intrinsic difficult
ies. An analysis of current publications demonstrates biased applicati
ons/results relating to equivalent problems. Modelling of the systems
by the RC analogy of heat transfer equations establishes the problems
connected with the structure of the apparatus and also the experimenta
l conditions to be fulfilled. Analysis of the equations highlights sev
eral possibilities that are used in part today. For instance, the redu
ction of noise and drift on the calorimeter output by a software appro
ach and the conditions to be attained with crucibles for increased acc
uracy.