F. Socorro et Mr. Derivera, MICRO-EFFECTS ON CONTINUOUS-INJECTION HEAT-CONDUCTION CALORIMETRY, JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 52(3), 1998, pp. 729-737
A localized-constant model involving two capacities reliably describes
two injection calorimeters: a mass-variation calorimeter and a consta
nt-volume calorimeter (TAM 2277 by Thermometric). The model distinguis
hes the place and the types of dissipation, and its parameters depend
on the rates and on the heat capacities of the liquids. IP the case of
the TAM 2277 calorimeter, the dependence between the detected heat of
mixing;md the injection rate is revealed. The proposed model permits
the inclusion of perturbations on the baseline originating from the te
mperature variation of the thermostat.