ENANTIOSELECTIVE SYNTHESIS OF (3S,5R,6E,8E)-DECA-6,8-DIEN-1,3,5-TRIOL, A NEW METABOLITE FROM STREPTOMYCES-FIMBRIATUS VIA ASYMMETRIC REACTION OF DIKETENE WITH 2,4-HEXADIENAL PROMOTED BY CHIRAL SCHIFF BASE-TITANIUM ALKOXIDE COMPLEXES

Authors
HAYASHI M KANEDA H OGUNI N
Citation
M. Hayashi et al., ENANTIOSELECTIVE SYNTHESIS OF (3S,5R,6E,8E)-DECA-6,8-DIEN-1,3,5-TRIOL, A NEW METABOLITE FROM STREPTOMYCES-FIMBRIATUS VIA ASYMMETRIC REACTION OF DIKETENE WITH 2,4-HEXADIENAL PROMOTED BY CHIRAL SCHIFF BASE-TITANIUM ALKOXIDE COMPLEXES, Tetrahedron : asymmetry, 6(10), 1995, pp. 2511-2516
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
10
Year of publication
1995
Pages
2511 - 2516
Database
ISI
SICI code
0957-4166(1995)6:10<2511:ESO(>2.0.ZU;2-3
Abstract
(3S,5R,6E,8E)-Deca-6,8-dien-1,3,5-triol, 6 which was isolated from the culture filtrate of Streptomyces fimbriatus has been synthesized effi ciently via the enantioselective reaction of diketene with 2,4-hexadie nal promoted by a novel chiral Schiff base-titanium alkoxide complex.