APPLICATION OF CUCURBITURIL DERIVATIVES TO DYE REMOVAL AGENT
Citation
K. Taketsuji et H. Tomioka, APPLICATION OF CUCURBITURIL DERIVATIVES TO DYE REMOVAL AGENT, Nippon kagaku kaishi, (10), 1998, pp. 670-678
Categorie Soggetti
Chemistry
SICI code
0369-4577(1998):10<670:AOCDTD>2.0.ZU;2-6
Abstract
Glycoluril-formaldehyde copolymer, obtained by the reaction of glycolu
ril with formaldehyde, is an insoluble compound in water and in most o
rganic solvents. This copolymer can be converted into a macrocyclic co
mpound named ''cucurbituril'' by further reaction. In this study, we f
ound that this copolymer effectively decolorized direct dyes and react
ive dyes aqueous solution and that the decolorization efficiency was n
ot only uninfluenced by temperature and pH, but also considerably bett
er than that of cucurbituril. Mechanism of decolorization was investig
ated by using model compounds for the dyes.