APPLICATION OF CUCURBITURIL DERIVATIVES TO DYE REMOVAL AGENT

Citation
K. Taketsuji et H. Tomioka, APPLICATION OF CUCURBITURIL DERIVATIVES TO DYE REMOVAL AGENT, Nippon kagaku kaishi, (10), 1998, pp. 670-678
Citations number
20
Categorie Soggetti
Chemistry
Journal title
ISSN journal
03694577
Issue
10
Year of publication
1998
Pages
670 - 678
Database
ISI
SICI code
0369-4577(1998):10<670:AOCDTD>2.0.ZU;2-6
Abstract
Glycoluril-formaldehyde copolymer, obtained by the reaction of glycolu ril with formaldehyde, is an insoluble compound in water and in most o rganic solvents. This copolymer can be converted into a macrocyclic co mpound named ''cucurbituril'' by further reaction. In this study, we f ound that this copolymer effectively decolorized direct dyes and react ive dyes aqueous solution and that the decolorization efficiency was n ot only uninfluenced by temperature and pH, but also considerably bett er than that of cucurbituril. Mechanism of decolorization was investig ated by using model compounds for the dyes.