MOLECULAR CLUSTERS AND CORRELATIONS IN LIQUID-AMMONIA

Authors
SARKAR S KARMAKAR AK JOARDER RN
Citation
S. Sarkar et al., MOLECULAR CLUSTERS AND CORRELATIONS IN LIQUID-AMMONIA, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 101(20), 1997, pp. 3702-3706
Citations number
25
Categorie Soggetti
Chemistry Physical
Journal title
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory → ACNP
ISSN journal
10895639
Volume
101
Issue
20
Year of publication
1997
Pages
3702 - 3706
Database
ISI
SICI code
1089-5639(1997)101:20<3702:MCACIL>2.0.ZU;2-J
Abstract
The available X-ray diffraction data of liquid ammonia at 4 degrees C exhibit considerable symmetry in the intermolecular structure in spite of hydrogen bonding. The intermolecular structure is modeled well by a heptamer cluster close to that of the solid state. The model reprodu ces reasonably well the available neutron diffraction and computer sim ulation data for liquid ammonia.