CATALYTIC ASYMMETRIC HYDROBORATION WITH HETEROTOPIC P-N LIGANDS - TRENDS IN ENANTIOSELECTIVITY WITH INCREASED STERIC DEMAND

Authors
VALK JM WHITLOCK GA LAYZELL TP BROWN JM
Citation
Jm. Valk et al., CATALYTIC ASYMMETRIC HYDROBORATION WITH HETEROTOPIC P-N LIGANDS - TRENDS IN ENANTIOSELECTIVITY WITH INCREASED STERIC DEMAND, Tetrahedron : asymmetry, 6(10), 1995, pp. 2593-2596
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
10
Year of publication
1995
Pages
2593 - 2596
Database
ISI
SICI code
0957-4166(1995)6:10<2593:CAHWHP>2.0.ZU;2-Y
Abstract
The rhodium complexes 1 and 3 catalyse asymmetric hydroboration with d iffering selectivity originating in the disparate steric environments of the catalysts.